学術論文 2001~

Syntheses of diaza(hetera)2[1.1.1.1]paracyclophanes by Chapman rearrangement

Hiroyuki Takemura,* Akino Morikawa, Mari Tanaka, Akane Tatsumi, Yukiko Kubota, Natsuko Kaji, Ayako Hasegawa, Fumiko Kumamoto, Tomoko Obara, Tetsuo Iwanaga, Katsuya Sako

Tetrahedron Letters, 2020, 61, 13, 151673-151678.
Synthesis and structures of N-(4-picolyl)azacalix[4]arene and its bridged derivatives

Hiroyuki Takemura,* Yukako Mogami, Kanae Okayama, Noriko Nagashima, Kana Orioka, Yuri Hayano, Asako Kobayashi, and Tetsuo Iwanaga, Katsuya Sako
J. Incl. Phenom. Macrocycl. Chem.
2019, 95, 3-4, 235-246, 2019.
Donor–Donor’–Acceptor Triads Based on [3.3]Paracyclophane with a 1,4-Dithiafulvene Donor and a Cyanomethylene Acceptor: Synthesis, Structure, and Electrochemical and Photophysical Properties

Katsuya Sako,* Tomoya Hasegawa, Hiroyuki Onda, Michito Shiotsuka, Motonori Watanabe, Teruo Shinmyozu, Sachiko Tojo, Mamoru
Fujitsuka, Tetsuro Majima, Yasukazu Hirao, Takashi Kubo, Tetsuo Iwanaga, Shinji Toyota, and Hiroyuki Takemura
Chem. Eur. J.
2018, 24, 11407 – 11416.

Synthesis of N,N-bridged azacalixarenes

Hiroyuki Takemura,* Katsuya Sako, Tesuo Iwanaga, Akane Tatsumi,
Yukako Mogami, Hiromi Watanabe, Miho Aoki, Shiho Yûki, Yuri Hayano, Mirei Itaka,  Tetrahedron 2018, 74 (16), 1991–2001.

Electrochemical Control of Bioluminescence by Blocking the Adsorption of the Bacterial Luciferase Using a Mercaptobipyridine Self-assembled Monolayer
Shinya YAMASAKI, Shuto YAMADA, Hiroyuki TAKEMURA, and Kô TAKEHARA ANALYTICAL SCIENCES, 2017, 33, 307-311.

Synthetic study and structure of cage-type cyclophane C36H36S6

Hiroyuki Takemura, Maiko Nagaoka, Chihiro Kawasaki, Kasumi Tokumoto, Noriko Tobita, Yuki Takano, Tetsuo Iwanaga

Tetrahedron Letters, 2017, 58, 1066–1070.

Synthesis and Radical Polymerization of Acrylamides Having One or Two 3-Carbazolylmethyl Moieties and Properties of the Formed Polymers

Keita Tani, Haruka Kato, Naoya Sakata, Toru Yashima, Koji Kubono, Kazushige Hori, Keisuke Tao, Kenta Goto, Fumito Tani, Hiroyuki Takemura, Keita Sakakibara, and Yoshinobu Tsujii,

Chem. Lett. 2017, 46, 85–87.
Synthesis of fluorocalix[4]arene and estimation of intramolecular C-F···HO hydrogen bond

Hiroyuki Takemura, Mio Inagaki, Yukari Hirata, and Tetsuo Iwanaga
J. Fluorine Chem., 2016, 182, 1-6.
Synthesis and properties of novel crown ether-annelated 4',5'-diaza-9'-(1,3-dithiole-2-ylidene)-fluorenes and their ruthenium(II) complexes

Katsuya Sako, Toshiaki Kakehi, Shota Nakano, Hiroyuki Oku, Xu Feng Shen, Tetsuo Iwanaga, Manami Yoshikawa, Kouta Sugahara, Shinji Toyota, Hiroyuki Takemura, Teruo Shinmyozu, Michito Shiotsuka, Hitoshi Tatemitsu
Tetrahedron Lett. 2014, 55, 749–752.
Synthesis of a hexacationic cyclophane and formation of EDA-type host-guest complexes

Hiroyuki Takemura, Saori Nakata, Akiko Inoue, and Ayaka Mishima
J. Incl. Phenom. Macrocycl. Chem.
2013, 77,483–487.
Synthesis and redox properties of p-conjugated 4,5-diazafluorene derivatives incorporating 9-cyanomethylene moiety as an electron acceptor

Katsuya Sako, Yasufumi Mugishima, Tetsuo Iwanaga, Shinji Toyota, Hiroyuki Takemura, Motonori Watanabe, Teruo Shinmyozu, Michito Shiotsuka, Hitoshi Tatemitsu
Tetrahedron Lett. 2011, 52, 5865-5868.
Synthesis of azacalixarenes via dihydrobenzoxazine derivatives of phenols

Hiroyuki Takemura, Asuka Takahashi, Haruka Suga, Mika Fukuda, and Tetsuo Iwanaga
Eur. J. Org. Chem. 2011, 3171-3177.
 N-(4-Phenylbutyl)azacalix[3.1.1.1]arene: Self-Inclusion of the Side Chain through CH···π Interactions

Hiroyuki Takemura, Yuka Yonebayashi, Takeshi Nakagaki, and Teruo Shinmyozu
Eur. J. Org. Chem. 2011, 1968-1971.
Intramolecular CF···HO hydrogen bond of 2-fluorophenyldiphenylmethanol

Hiroyuki Takemura, Megumi Kaneko, Katsuya Sako, and Tetsuo Iwanaga
New J. Chem. 2009, 33, 2004-2006.
C-F∙∙∙HO hydrogen bond in 8-Fluoro-4-Methyl-1-Naphthol

Hiroyuki Takemura, Risako Ueda, Tetsuo Iwanaga
J. Fluorine Chem. 2009, 130, 684-688.
Interaction of boric acid with salicyl derivatives as an anchor group of boron selective adsorbents

Yoshinobu Miyazaki, Hidenobu Matsuo, Takao Fujimori, Hiroyuki Takemura, Shiro Matsuoka, Tadashi Okobira, Kazuya Uezu and Kazuhisa Yoshimura
Polyhedron 2008, 27, 2785-2790.
A Convenient Synthesis of Trifluoroacetamide Derivatives of Diaza[32]- and Triaza[33]cyclophanes

Hideki Okamoto, Hiroyuki Takemura, and Kyosuke Satake
SYNTHESIS 2008, 39-44.

Synthesis and Properties of Partially-overlapped [3.n](3,9)Carbazolophanes

Keita Tani,
Shinya Yamamoto, Koji Kubono, Kazushige Hori, Yasuo Tohda, Hiroyuki Takemura, Yosuke Nakamura, Jun Nishimura, Hiroaki Benten, Hideo Ohkita, Shinzaburo Ito, and Masahide Yamamoto,
Chem. Lett. 2007, 36, (No.3), 460-461.

Bis(1,3-dithiol-2-ylidene)-[3.3]paracyclophanes: orthogonal intramolecular charge transfer interaction

Katsuya Sako, Yukiharu Mase, Yousuke Kato, Tetsuo Iwanaga, Teruo Shinmyozu,

Hiroyuki Takemura, Mitsuhiro Ito, Kousuke Sasaki, and Hitoshi Tatemitsu
Tetrahedron Letters, 2006, 47, 9151?9154.

C-F・・・Rb+ Interaction in a Fluorinated Cage Compound Complex

Hiroyuki Takemura, Tetsuo Iwanaga,
and Teruo Shinmyozu
Tetrahedron Letters, 2006, 47, 8989-8991.

Cyclophanes within Cyclophanes: The Synthesis of a Pyromellitic Diimide-Based Macrocycle as a Structural Unit in a Molecular Tube and Its Inclusion Phenomena

Tetsuo Iwanaga, Ryoma Nakamoto, Mikio Yasutake, Hiroyuki Takemura, Katsuya Sako, Teruo Shinmyozu
Angew. Chem., Int. Ed. Engl., 2006, 45, 3643 -3647.
Li+・・・ π Interaction in Coronene-Azacrown Ether System

Hiroyuki Takemura and Katsuya Sako
Tetrahedron Letters,2005, 46, 8169-8172.
A New Synthetic Method of (Aza)n[3n]cyclophanes By Diethyl Phosphoramidates

Hiroyuki Takemura, Gang Wen, Teruo Shinmyozu

Synthesis, 2005, No. 17, 2845-2850.
Structures and C-H ・・・ π Interactions in DMF Inclusion Complexes of Homoazacalix[4]arenes

Hiroyuki Takemura,
Tetsuo Iwanaga, and Teruo Shinmyozu
Tetrahedron Letters, 2005, 46, 6687-6690.
A Survey of Interaction in Some Macrocyclic Compounds

Hiroyuki Takemura
Current Organic Chemistry, 2005, 9, 521-533.
Pyrene-Azacrown Ether Hybrid: Cation-π Interaction

Hiroyuki Takemura, Hiroaki Nakamichi, Katsuya Sako
Tetrahedron Letters, 2005, 46, 2063-2066.
The Ar-Cl・・・HO hydrogen bond of 6-chloro-9-hydroxy-[3.3]metacyclophane

Hiroyuki Takemura, Masayuki Kotoku, Mikio Yasutake, Teruo Shinmyozu
J. Chem. Res., 2004, 834-835.
Synthesis and Redox Behavior of Wurster Blue Cyclophanes

Hiroyuki Takemura, Ko Takehara, Masafumi Ata
Eur. J. Org. Chem. 2004, 4936-4941.
9-Fluoro-18-hydroxy-[3.3]metacyclophane: Synthesis and Estimation of C-F・・・HO Hydrogen Bond

Hiroyuki Takemura, Masayuki Kotoku, Mikio Yasutake, Teruo Shinmyozu
Eur. J. Org. Chem. 2004, 2019-2024.
11B NMR study on the interaction of boric acid with Azomethine H

Hidenobu Matsuo, Yoshinobu Miyazaki, Hiroyuki Takemura, Shiro Matsuoka, Hirofumi Sakashita, Kazuhiza Yoshimura
Polyhedron 2004, 23(6), 955-961.
Synthesis and Properties of Carbazole-terephthalate Cyclophane

Keita Tani, Koh Matsumura, Eiichi Togo, Kazushige Hori, Yasuo Tohda, Hiroyuki Takemura, Hideo Ohkita, Shinzaburo Ito, Masahide Yamamoto
Chem. Lett. 2003, 32, 910-911.
A uranyl ion complex of N-methyl-p-tert-butyldihomoammoniocalix[4]arene with diaqua-dipyridine lithium as a counter-ion

Pierre Thuery and Hiroyuki Takemura
Acta Cryst. 2003, C59, 384-386.
Synthesis and Properties of Photo-responsive Tetrathiafulvalene derivatives

K. Sako, M. Kusakabe, H. Fujino, S. X. Feng, H. Takemura, T. Shinmyozu, H. Tatemitsu
Synthetic Metals 2003, 137, 899-900.
A Comparison of Coordination Ability of Hetero Atoms: A Li+ and Na+ Selective Pyridinophane-Based Cryptand

Hiroyuki Takemura, Hiroyuki Nakamichi, Rika Nogita, Tetsuo Iwanaga, Mikio Yasutake and Teruo Shinmyozu

Tetrahedron Letters 2003, 44, 5087-5089.
Structurally Isomeric Two Pyridino Macrocycles: Complexation and Structures

Hiroyuki Takemura, Noriyoshi Kon, Mikio Yasutake, Teruo Shinmyozu

Tetrahedron 2003, 59, 427-431.
Synthesis and Properties of [2.2]Paracyclo- and [2.2](1,4)Naphthaleno-(3,6)carbazolophanes

Keita Tani, Koh Matsumura, Kazushige Hori, Yasuo Tohda, Hiroyuki Takemura, Hideo Ohkita, Shinzaburo Ito, Masahide Yamamoto
Chemistry Letters, 2002, 934-935.
炭素に共有結合したフッ素原子 (C-F):新しいカチオンドナーとしての性質
Fluorine Atom Covalently Bonded to Carbon Atom: Properties as New Cation Donor


武村 裕之
有機合成化学協会誌 2002, 60, (No.10), 963-973.
Azacalixarenes: Synthesis, Complexation, and Structures

Hiroyuki Takemura
J. Inclusion Phenom. 2002, 42, 169-186.
Base-induced variation of the coordination mode in a uranyl homoazacalixarene complex

Pierre Thuery, Martine Nierlich, Jacques Vicens, Hiroyuki Takemura
Polyhedron 2001, 20, 3183?3187.
Synthesis and photophysical properties of [3.3](3,9)carbazolophanes

Keita Tani, Yasuo Tohda, Hiroyuki Takemura, Hideo Ohkita, Shinzaburo Ito, Masahide Yamamoto
Chem. Commun. 2001, 1914-1915.
A Study of C-F・・・M+ Interaction: Metal Complexes of Fluorine-Containing Cage Compounds

Hiroyuki Takemura, Sachiko Nakashima, Noriyoshi Kon, Mikio Yasutake, Teruo Shinmyozu, Takahiko Inazu
J. Am. Chem. Soc. 2001, 123, 9293-9298.
Alternative General Synthetic Routes to [2.2]Cyclophanes and [3.2]Cyclophanes from [3.3]Cyclophane-2,11-diones by Photodecarbonylation, and a Structural Study of [3.2]Metacyclophanes

Hajime Isaji, Mikio Yasutake, Hiroyuki Takemura, Katsuya Sako, Hitoshi Tatemitsu, Takahiko Inazu, Teruo Shinmyozu
Eur. J. Org. Chem. 2001, 2487-2499.
A study of C-F・・・M+ Interaction: Alkali Metal Complexes of the Fluorine-Containing Cage Compound

Hiroyuki Takemura, Noriyoshi Kon, Masayuki Kotoku, Sachiko Nakashima, Kazuhiro Otsuka, Mikio Yasutake, Teruo Shinmyozu, Takahiko Inazu
J. Org. Chem. 2001, 66, 2778-2783.
Oxa- and Azacalixarenes as Ligands for Uranyl Ions: ? Evidence for Two Different Complexation Modes

Pierre Thuery, Martine Nierlich, Jacques Vicens, Bernardo Masci, Hiroyuki Takemura
Eur. J. Inorg. Chem. 2001, 637-643.


総説

炭素に共有結合したフッ素原子 (C-F):新しいカチオンドナーとしての性質

Fluorine Atom Covalently Bonded to Carbon Atom: Properties as New Cation Donor

武村 裕之
有機合成化学協会誌 2002, 60, (No.10), 963-973.

Fluorinated Macrocycles: A New Donor (C-F) For Cations
Hiroyuki Takemura
“Cyclophane Chemistry for the 21st Century”
Transworld Research Network, India, 2003, pp 127-148
Hiroyuki Takemura, Ed.


New Synthetic Method of (Aza)n[3n]cyclophanes


Hiroyuki Takemura, Gang Wen, and Teruo Shinmyozu
‘New Trends in Structural Organic Chemistry’

Transworld Research Network
, India, 2005, pp 125-144.
Hiroyuki Takemura, Ed.



[1n]Paracyclophanes
Hiroyuki Takemura
Current Organic Chemistry, 2009, 13, 1633-1653.



紀要

教育ノート 有機化学学生実験を安全に行うための工夫と考察

An invention to perform safe student experiment in organic chemistry.

武村裕之 Mem. Fac. Sci., Japan Women’s Univ., 2018, 26, 9-11.

論説・エッセイ・その他

〇 飛び跳ねる結晶 “Jumping Crystals”

武村 裕之

「化学」 2005年, 60巻、11号、p46-49

 化学平衡を表す矢印について
武村 裕之
化学と教育 フォーラム
2005年、53巻、9号、p 514


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